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Modacrylic fiber features

Inherently FR
• Self-extinguishing when flame is removed
Char former
• With certain additives, fibers char, forming a flame barrier, especially in the presence of cellulosic fibers.
Chemically resistant
• Resistant to acids and bases
Thermal plastic
• Thermo-forming, moldable
No melting phase, so no dripping
• The dripping of molten polymer fibers can cause injury and spread the fire. Prevents polyester fibers from melting, also.
Dyeable
• Using basic dyes
Natural hand
• A softness similar to animal fur
Thermal insulator
• Feels light weight, yet it keeps you warm

Modacrylic fiber is a wet-spun halogen-substituted hydrocarbon made, primarily, from acrylonitrile (CH2=CHCN) / vinyl chloride (CH2=CHCl) or vinylidene chloride (CH2=CCl2) copolymer.

Modacrylic fibers, by FTC (Federal Trade Commission) definition, must have a polymerized acrylonitrile (see chemical structures below) content that is greater than 35% and less than 85% by weight. In contrast, acrylic fibers must have at least 85% polymerized acrylonitrile by weight. See FTC Rules and Regulations (in new window) Under the Textile Fiber Products Identification Act, 16 CFR Part 303. Modacrylic retains many of the favorable characteristics of acrylic fiber.

 

Chemical structures

— (CH2 CH)n
  ½
  CºN
Polyacrylonitrile
 
— (CH2 CH)m (CH2 CH)n
  ½   ½
  CºN   Cl
acrylonitrile / vinyl chloride
copolymer modacrylic
    
    Cl
    ½
— (CH2 CH)m (CH2 C)n
  ½   ½
  CºN   Cl
acrylonitrile / vinylidene chloride
copolymer modacrylic
 
More about modacrylic precursors
Modacrylic fiber overview (in new window) by the American Fiber Manufacturers Association (AFMA) and the Fiber Bureau